Biomethanation
www.Biomethanation.com
We
provide Methane Gas Recovery
products and services which provide fuel for generating power as well as
cogeneration and trigeneration systems.
BioMethane
is generated from Anaerobic Digesters,
Anaerobic Lagoons, Biomass
Gasification, Biogas Recovery, BioMethane,
Concentrated Animal
Feeding Operations Landfill Gas
to Energy, and Methane Gas Recovery.
Unlike most companies, we are equipment supplier/vendor neutral. This
means we help our clients select the best equipment for their specific
application. This approach provides our customers with superior
performance, decreased operating expenses and increased return on
investment.
Renewable
Energy Technologies provides products and services relating to the biomethane
produced from Publicly
Owned Treatment Works and Wastewater
Treatment plants.
Cooler,
Cleaner, Greener Power & Energy Solutions project
development services are one of our specialties. These projects are Kyoto
Protocol compliant and generate clean energy and significantly fewer
greenhouse gas emissions. Unlike most companies, we are equipment
supplier/vendor neutral. This means we help our clients select the best
equipment for their specific application. This approach provides our
customers with superior performance, decreased operating expenses and
increased return on investment.
Renewable
Energy
Technologies provides
project development services that generate clean energy and significantly
reduce greenhouse gas emissions and
carbon dioxide emissions.
Included in this are our
turnkey "ecogeneration"
products and services which includes renewable
energy technologies, waste to energy,
waste to watts and waste
heat recovery solutions. Other project development
technologies include; Anaerobic Digester,
Anaerobic Lagoon, Biogas
Recovery, BioMethane, Biomass
Gasification, and Landfill Gas To
Energy, project development services.
Products and
services provided by Renewable Energy
Technologies includes the following
power and energy project development services:
-
Project
Engineering Feasibility & Economic Analysis Studies
-
Engineering,
Procurement and Construction
-
Environmental
Engineering & Permitting
-
Project
Funding & Financing Options; including Equity Investment, Debt
Financing, Lease and Municipal Lease
-
Shared/Guaranteed
Savings Program with No Capital Investment from Qualified Clients
-
Project
Commissioning
-
3rd
Party Ownership and Project Development
-
Long-term
Service Agreements
-
Operations
& Maintenance
-
Green
Tag (Renewable Energy Credit, Carbon Dioxide Credits, Emission
Reduction Credits) Brokerage Services; Application and Permitting
For
more information: call us at: 832-758-0027
We
are Renewable Energy
Technologies specialists and develop clean power and energy projects
that will generate a "Renewable
Energy Credit," Carbon
Dioxide Credits and Emission
Reduction Credits. Some of our products and services solutions
and technologies include; Absorption
Chillers, Adsorption Chillers, Automated
Demand Response, Biodiesel
Refineries, Biofuel Refineries, Biomass
Gasification, BioMethane, Canola
Biodiesel, Coconut Biodiesel, Cogeneration,
Concentrating Solar Power, Demand
Response Programs, Demand Side
Management, Energy
Conservation Measures, Energy
Master Planning, Engine Driven
Chillers, Geothermal Heatpumps,
Groundsource Heat Pumps, Solar
CHP, Solar Cogeneration, Rapeseed
Biodiesel, Solar Electric Heat
Pumps, Solar Electric Power
Systems, Solar Heating and
Cooling, Solar Trigeneration, Soy
Biodiesel, Trigeneration, and Watersource
Heat Pumps.
What
is BioMethane, BioMethanation and
Methanogenesis?
BioMethane is generated from organic materials as they decay.
Sources of BioMethane include; landfills, POTW's/Wastewaster Treatment
Systems, and from animal operations where manure can be collected and the
BioMethane is generated from anaerobic digesters where the manure
decomposes.
BioMethane,
after installation of the requisite equipment, is essentially free,
as opposed to buying natural gas, presently costing around $6.00/mmbtu.
Methanogenesis
is the production of CH4 and CO2 by biological processes that are carried
out by methanogens.
Again, unlike the price of natural gas, which has been around $6.00/mmbtu
for the past year.
More
About Biomass Gasification and BioMethanation Technology
The
process of Biomass Gasification produces BioMethane. BioMethane is also
produced in anaerobic digesters, in the process called anaerobic
digestion. BioMethane is a renewable energy resource, as opposed to
natural gas (methane), which is a non-renewable energy resource.
BioMethane has similar qualities of methane and both are used in
interchangeably, and each may be a substitute for the other.
The
production and disposal of large quantities of organic and biodegradable
waste without adequate or proper treatment results in widespread
environmental pollution. Some waste streams can be treated by conventional
methods like aeration. Compared to the aerobic method, the use of
anaerobic digesters in processing these waste streams provides greater
economic and environmental benefits and advantages.
As
previously stated, Biomethanation is the process of conversion of organic
matter in the waste (liquid or solid) to BioMethane (sometimes referred to
as "BioGas) and manure by microbial action in the absence of air,
known as "anaerobic digestion."
Conventional digesters such as sludge digesters and anaerobic CSTR
(Continuous Stirred Tank Reactors) have been used for many decades in
sewage treatment plants for stabilizing the activated sludge and sewage
solids.
Interest
in BioMethanation as an economic, environmental and energy-saving waste
treatment continues to gain greater interest world-wide and has led to the
development of a range of anaerobic reactor designs. These high-rate,
high-efficiency anaerobic digesters are also referred to as "retained
biomass reactors" since they are based on the concept of retaining
viable biomass by sludge immobilization.
Biomass Gasification and the Production of BioMethane
Biomass is a renewable energy resource which includes a wide variety if
organic resources. A few of these include wood, agricultural
residue/waste, and animal manure.
Biomass Gasification is the process in which BioMethane is produced in the
BioMass Gasification process. The BioMethane is then used like any other
fuel, such as natural gas, which is not a renewable fuel.
Historically, biomass use has been characterized by low btu and low
efficiencies. However, today biomass gasification is gaining world-wide
recognition and favor due to the economic and environmental benefits. In
terms of economic benefits, the cost of the BioMethane is essentially
free, after the cost of the equipment is installed. BioMethane, probably
the most important and efficient energy-conversion technology for a wide
variety of biomass fuels. The large-scale deployment of efficient
technology along with interventions to enhance the sustainable supply of
biomass fuels can transform the energy supply situation in rural areas.
It has the potential to become the growth engine for rural development in
the country.
Principles of Biomass Gasification
Biomass fuels such as firewood and agriculture-generated residues and
wastes are generally organic. They contain carbon, hydrogen, and
oxygen along with some moisture. Under controlled conditions,
characterized by low oxygen supply and high temperatures, most
biomass materials can be converted into a gaseous fuel known as producer
gas, which consists of carbon monoxide, hydrogen, carbon dioxide, methane
and nitrogen. This thermo-chemical conversion of solid biomass into
gaseous fuel is called biomass gasification. The producer gas so produced
has low a calorific value (1000-1200 Kcal/Nm3), but can be burnt with a
high efficiency and a good degree of control without emitting smoke. Each
kilogram of air-dry biomass (10% moisture content) yields about 2.5 Nm3 of
producer gas. In energy terms, the conversion efficiency of the
gasification process is in the range of 60%-70%.
Multiple Advantages of Biomass Gasification in
Methane Production
Conversion of solid biomass into combustible gas has all the advantages
associated with using gaseous and liquid fuels such as clean combustion,
compact burning equipment,
high thermal efficiency and a good degree of control. In locations, where
biomass is already available at reasonable low prices (e.g. rice mills) or
in industries using fuel wood, gasifier systems offer definite economic
advantages. Biomass gasification technology is also environment-friendly,
because of the firewood savings and reduction in CO2 emissions.
Biomass gasification technology has the potential to replace diesel and
other petroleum products in several applications, foreign exchange.
Applications for Biomass Gasification
Thermal applications: cooking, water boiling, steam generation, drying
etc.
Motive power applications: Using producer gas as a fuel in IC engines for
applications such as water pumping Electricity generation: Using producer
gas in dual-fuel mode in diesel engines/as the only fuel in spark ignition
engines/in gas turbines.
Publicly Owned Treatment Works ("POTW's") or Wastewater
Treatment Systems
More
and more, cities, counties and municipalities are faced with greater
environmental compliance issues relating to their municipally-owned
landfills, Publicly Owned Treatment Works ("POTW's") or
Wastewater Treatment Systems.
A
city's landfill and/or POTW provides an excellent opportunity for cities
to reduce their emissions as well as provide an additional revenue stream.
These facilities may have valuable gases that our company recovers and
pipes to one of our clean, environmentally-friendly cogeneration or
trigeneration energy systems.
Our
company provides economic and ecological
solutions for cities and municipalities and
provide a new cash flow simultaneously. We offer turn-key solutions
for cities that includes the preliminary feasibility analysis, engineering
and design, project management, permitting and commissioning. We
provide very attractive financing packages for cities that does not add to
a city's liability, yet provides a valuable new revenue stream. And,
we are also able to offer a turn-key solution for qualified municipalities
that includes our company owning, operating and maintaining the onsite
power and energy plant.
At
the heart of the system is a (Bio) Methane Gas Recovery system similar
those used in Flare Gas Recovery or Vapor Recovery Units. Methane
Gas Recovery, Flare Gas Recovery, Vapor Recovery, Waste to Energy and
Vapor Recovery Units all recover valuable "waste" or vented
fuels that can be used to provide fuel for an onsite power generation
plant. Our waste-to-energy and waste to fuel systems significantly
or entirely, reduces your facility's emissions (such as
NOx
,
SOx, H2S, CO
, CO2 and other Hazardous Air Pollutants/Greenhouse Gases) and convert
these valuable emissions from an environmental problem into a new cash
revenue stream and profit center.
Methane
Gas Recovery and vapor recovery units can be located in hundreds of
applications and locations. At a landfill, Wastewaster Treatment
System (or Publicly Owned Treatment Works - "POTW") gases from
the facility can be captured from the anaerobic digesters, and manifolded/piped
to one of our onsite power generation plants, and make, essentially,
"free" electricity for your facility's use. These
associated "biogases" that are generated from municipally
owned landfills or wastewater treatment plants have low btu content or
heating values, ranging around 550-650 btu's.
This makes them
unsuitable for use in natural gas applications. When burned as fuel to
generate electricity, however, these gases become a valuable source of
"renewable" power and energy for the facility's use or resale to
the electric grid.
Additionally,
if heat (steam and/or hot water) is required, we will incorporate our
cogeneration or trigeneration system into the project and provide some, or
all, of your hot water/steam requirements. Similarly, at crude oil
refineries, gas processing plants, exploration and production sites, and
gasoline storage/tank farm site, we convert your facility's "waste
fuel" and environmental liabilities into profitable,
environmentally-friendly solutions.
Our
Methane Gas Recovery systems are designed and engineered for these
specific applications. It is important to note that there are many
internal combustion engines or combustion turbines that are NOT suited for
these applications. Our systems are engineered precisely for your
facility's application, and our engineers know the engines and turbines
that will work as well as those that don't. More importantly, we are
vendor and supplier neutral! Our only concerns are for the optimum
system solution
for your company, and we look past brand names and sales propaganda to
determine the optimum system, which may incorporate either one or more;
gas engine genset(s) or gas turbine genset(s), in cogeneration or
trigeneration mode - in trigeneration mode, we incorporate absorption
chillers to make chilled water for process or air-conditioning, fuel
gas conditioning equipment and gas compressor(s).
Our
turn-key systems includes design, engineering, permitting, project
management, commissioning, as well as financing for our qualified
customers. Additionally, we may be interested in owning and operating the
flare gas recovery or vapor recovery units. For these applications, there
is no investment required from the customer.
For
more information, please provide us with the following information about
the flare gas or vapor:
-
Type
of gas being flared or vented (methane, bio-gas, digester, landfill,
etc.).
-
Chromatograph
Fuel/Gas analysis which provides us with the btu's (heating value) and
the composition of the gas and its' impurities such as methane (and
the percentage of methane), soloxanes, carbon dioxide, hydrogen,
hydrogen sulfide, and any other hydrocarbons.
-
Total
amount of gas available, from all sources, at the facility.
What
is an Anaerobic Digester?
An
Anaerobic Digester is a device for optimizing the anaerobic digestion of
biomass and/or animal manure, and possibly to recover biogas also referred
to as BioMethane for energy production.
Digester types include batch, complete mix, continuous flow (horizontal or
plug-flow, multiple-tank, and vertical tank), and covered lagoon.
What is Anaerobic Digestion?
Anaerobic
digestion is a biological process that produces a gas principally composed
of methane (CH4) and carbon dioxide (CO2) otherwise known as biogas. These
gases are produced from organic wastes such as livestock manure, food
processing waste, etc.
Anaerobic processes could either occur naturally or in a controlled
environment such as a biogas plant. Organic waste such as livestock manure
and various types of bacteria are put in an airtight container called
digester so the process could occur. Depending on the waste feedstock and
the system design, biogas is typically 55 to 75 percent pure methane.
State-of-the-art systems report producing biogas that is more than 95
percent pure methane.
The
U.S.
EPA
AgSTAR Program Background
The
U.S. EPA AgSTAR is an outreach program designed to reduce methane
emissions from livestock waste management operations by promoting the use
of biogas recovery systems. A biogas recovery system is an anaerobic
digester with biogas capture and combustion to produce electricity, heat
or hot water. Biogas recovery systems are effective at confined livestock
facilities that handle manure as liquids and slurries, typically swine and
dairy farms. Anaerobic digester technologies provide enhanced
environmental and financial performance when compared to traditional waste
management systems such as manure storages and lagoons. Anaerobic
digesters are particularly effective in reducing methane emissions but
also provide other air and water pollution control opportunities. AgSTAR
provides an array of information and tools designed to assist producers in
the evaluation and implementation these systems, including:
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Conducting
farm digester extension events and conferences
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Providing
“How-To” project development tools and industry listings
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Conducting
performance characterizations for digesters and conventional waste
management systems
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Operating
a toll free hotline
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Providing
farm recognition for voluntary environmental initiatives
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Collaborating
with federal and state renewable energy, agricultural, and
environmental programs
Methane
(and Biomethane) Emissions from Animal Waste Management
Methane
emissions occur whenever animal waste is managed in anaerobic conditions.
Liquid manure management systems, such as ponds, anaerobic lagoons, and
holding tanks create oxygen free environments that promote methane
production. Manure deposited on fields and pastures, or otherwise handled
in a dry form, produces insignificant amounts of methane. Currently,
livestock waste contributes about 8 percent of human-related methane
emissions in the
U.S.
Given
the trend toward larger farms, liquid manure management is expected to
increase. For more information on international emissions, projections,
and mitigation costs, see International
Analyses.
Biomethane
from Anaerobic Digesters
Methane
(and Biomethane) is a gas that contains molecules of methane with one atom of carbon and
four atoms of hydrogen (CH4 ). It is the major component of the
"natural" gas used in many homes for cooking and heating. It is
odorless, colorless, and yields about 1,000 British Thermal Units (Btu)
[252 kilocalories (kcal)] of heat energy per cubic foot (0.028 cubic
meters) when burned. Natural gas is a fossil fuel that was created eons
ago by the anaerobic decomposition of organic materials. It is often found
in association with oil and coal.
The
same types of anaerobic bacteria that produced natural gas also produce
methane today. Anaerobic bacteria are some of the oldest forms of life on
earth. They evolved before the photosynthesis of green plants released
large quantities of oxygen into the atmosphere. Anaerobic bacteria break
down or "digest" organic material in the absence of oxygen and
produce "biogas" as a waste product. (Aerobic decomposition, or
composting, requires large amounts of oxygen and produces heat.) Anaerobic
decomposition occurs naturally in swamps, water-logged soils and rice
fields, deep bodies of water, and in the digestive systems of termites and
large animals. Anaerobic processes can be managed in a
"digester" (an airtight tank) or a covered lagoon (a pond used
to store manure) for waste treatment. The primary benefits of anaerobic
digestion are nutrient recycling, waste treatment, and odor control.
Except in very large systems, biogas production is a highly useful but
secondary benefit.
Biogas
produced in anaerobic digesters consists of methane (50%-80%), carbon
dioxide (20%-50%), and trace levels of other gases such as hydrogen,
carbon monoxide, nitrogen, oxygen, and hydrogen sulfide. The relative
percentage of these gases in biogas depends on the feed material and
management of the process. When burned, a cubic foot (0.028 cubic meters)
of biogas yields about 10 Btu (2.52 kcal) of heat energy per percentage of
methane composition. For example, biogas composed of 65% methane yields
650 Btu per cubic foot (5,857 kcal/cubic meter).
Anaerobic
Digester
Designs
Anaerobic
digesters are made out of concrete, steel, brick, or plastic. They are
shaped like silos, troughs, basins or ponds, and may be placed underground
or on the surface. All designs incorporate the same basic components: a
pre-mixing area or tank, a digester vessel(s), a system for using the
biogas, and a system for distributing or spreading the effluent (the
remaining digested material).
There
are two basic types of digesters: batch and continuous. Batch-type
digesters are the simplest to build. Their operation consists of loading
the digester with organic materials and allowing it to digest. The
retention time depends on temperature and other factors. Once the
digestion is complete, the effluent is removed and the process is
repeated.
In
a continuous digester, organic material is constantly or regularly fed
into the digester. The material moves through the digester either
mechanically or by the force of the new feed pushing out digested
material. Unlike batch-type digesters, continuous digesters produce biogas
without the interruption of loading material and unloading effluent. They
may be better suited for large-scale operations. There are three types of
continuous digesters: vertical tank systems, horizontal tank or plug-flow
systems, and multiple tank systems. Proper design, operation, and
maintenance of continuous digesters produce a steady and predictable
supply of usable biogas.
Many
livestock operations store the manure they produce in waste lagoons, or
ponds. A growing number of these operations are placing floating covers on
their lagoons to capture the biogas. They use it to run an
engine/generator to produce electricity.
The
Digestion Process
Anaerobic
decomposition is a complex process. It occurs in three basic stages as the
result of the activity of a variety of microorganisms. Initially, a group
of microorganisms converts organic material to a form that a second group
of organisms utilizes to form organic acids. Methane-producing (methanogenic)
anaerobic bacteria utilize these acids and complete the decomposition
process.
A
variety of factors affect the rate of digestion and biogas production. The
most important is temperature. Anaerobic bacteria communities can endure
temperatures ranging from below freezing to above 135° Fahrenheit (F)
(57.2° Centigrade [C]), but they thrive best at temperatures of about 98°F
(36.7°C) (mesophilic) and 130°F (54.4°C) (thermophilic). Bacteria
activity, and thus biogas production, falls off significantly between
about 103° and 125°F (39.4° and 51.7°C) and gradually from 95° to 32°F
(35° to 0°C).
In
the thermophilic range, decomposition and biogas production occur more
rapidly than in the mesophilic range. However, the process is highly
sensitive to disturbances such as changes in feed materials or
temperature. While all anaerobic digesters reduce the viability of weed
seeds and disease-producing (pathogenic) organisms, the higher
temperatures of thermophilic digestion result in more complete
destruction. Although digesters operated in the mesophilic range must be
larger (to accommodate a longer period of decomposition within the tank
[residence time]), the process is less sensitive to upset or change in
operating regimen.
To
optimize the digestion process, the digester must be kept at a consistent
temperature, as rapid changes will upset bacterial activity. In most areas
of the United States, digestion vessels require some level of insulation
and/or heating. Some installations circulate the coolant from their
biogas-powered engines in or around the digester to keep it warm, while
others burn part of the biogas to heat the digester. In a properly
designed system, heating generally results in an increase in biogas
production during colder periods. The trade-offs in maintaining optimum
digester temperatures to maximize gas production while minimizing expenses
are somewhat complex. Studies on digesters in the north-central areas of
the country indicate that maximum net biogas production can occur in
digesters maintained at temperatures as low as 72°F (22.2°C).
Other
factors affect the rate and amount of biogas output. These include pH,
water/solids ratio, carbon/nitrogen ratio, mixing of the digesting
material, the particle size of the material being digested, and retention
time. Pre-sizing and mixing of the feed material for a uniform consistency
allows the bacteria to work more quickly. The pH is self-regulating in
most cases. Bicarbonate of soda can be added to maintain a consistent pH,
for example when too much "green" or material high in nitrogen
content is added. It may be necessary to add water to the feed material if
it is too dry, or if the nitrogen content is very high. A carbon/nitrogen
ratio of 20/1 to 30/1 is best. Occasional mixing or agitation of the
digesting material can aid the digestion process. Antibiotics in livestock
feed have been known to kill the anaerobic bacteria in digesters. Complete
digestion, and retention times, depend on all of the above factors.
Producing
and Using Biomethane
As
long as proper conditions are present, anaerobic bacteria will
continuously produce biogas. Minor fluctuations may occur that reflect the
loading routine. Biogas can be used for heating, cooking, and to operate
an internal combustion engine for mechanical and electric power. For
engine applications, it may be advisable to scrub out hydrogen sulfide (a highly corrosive and toxic gas). Very large-scale systems/producers may be
able to sell the gas to natural gas companies, but this may require
scrubbing out the carbon dioxide.
Using
the Effluent
The
material drawn from the digester is called sludge, or effluent. It is rich
in nutrients (ammonia, phosphorus, potassium, and more than a dozen trace
elements) and is an excellent soil conditioner. It can also be used as a
livestock feed additive when dried. Any toxic compounds (pesticides, etc.)
that are in the digester feedstock material may become concentrated in the
effluent. Therefore, it is important to test the effluent before using it
on a large scale.
Economics
Anaerobic
digester system costs vary widely. Systems can be put together using
off-the-shelf materials. There are also a few companies that build system
components. Sophisticated systems have been designed by professionals
whose major focus is research, not low cost. Factors to consider when
building a digester are cost, size, the local climate, and the
availability and type of organic feedstock material.
In
the United States, the availability of inexpensive fossil fuels has
limited the use of digesters solely for biogas production. However, the
waste treatment and odor reduction benefits of controlled anaerobic
digestion are receiving increasing interest, especially for large-scale
livestock operations such as dairies, feedlots, and slaughterhouses. Where
costs are high for sewage, agricultural, or animal waste disposal, and the
effluent has economic value, anaerobic digestion and biogas production can
reduce overall operating costs. Biogas production for generating cost
effective electricity requires manure from more than 150 large animals.
Below-ground,
concrete anaerobic digesters have proven to be especially useful to
agricultural communities in parts of the world such as China, where fossil
fuels and electricity are expensive or unavailable. The primary purpose of
these anaerobic digesters is waste (sewage) treatment and fertilizer
production. Biogas production is secondary.
Accomplishments
The AgSTAR Program has been very successful in encouraging the development
and adoption of anaerobic digestion technology. Since the establishment of
the program in 1994, the number of operational digester systems has
doubled. This has produced significant environmental and energy benefits,
including methane emission reductions of approximately 124,000 metric tons
of carbon equivalent and annual energy generation of about 30 million kWh.
The graph below shows the historical use of biogas recovery technology for
animal waste management.
The
development of anaerobic digesters for livestock manure treatment and
energy production has accelerated at a very fast pace over the past few
years. Factors influencing this market demand include: increased technical
reliability of anaerobic digesters through the deployment of successful
operating systems over the past five years; growing concern of farm owners
about environmental quality; an increasing number of state and federal
programs designed to cost share in the development of these systems; and
the emergence of new state energy policies (such as net metering
legislation) designed to expand growth in reliable renewable energy and
green power markets.
In
the past 2 years alone, the number of operational digester systems has
increased by 30%. For more detailed information on anaerobic digester use
in the
U.S.
, go to the Guide
to Operational Systems or see the AgSTAR
2003 Digest
The
process of anaerobic digestion consists of three steps.
The first step is the decomposition (hydrolysis) of plant or animal
matter. This step breaks down the organic material to usable-sized
molecules such as sugar. The second step is the conversion of decomposed
matter to organic acids. And finally, the acids are converted to methane
gas.
Process temperature affects the rate of digestion and should be maintained
in the mesophillic range (95 to 105 degrees Fahrenheit) with an optimum of
100 degrees F. It is possible to operate in the thermophillic range (135
to 145 degrees F), but the digestion process is subject to upset if not
closely monitored.
Many anaerobic digestion technologies are commercially available and have
been demonstrated for use with agricultural wastes and for treating
municipal and industrial wastewater.
At Royal Farms No. 1 in Tulare, California, hog manure is slurried and
sent to a Hypalon-covered lagoon for biogas generation. The collected
biogas fuels a 70 kilowatt (kW) engine-generator and a 100 kW
engine-generator. The electricity generated on the farm is able to meet
monthly electric and heat energy demand.
Given the success of this project, three other swine farms (Sharp Ranch,
Fresno and Prison Farm) have also installed floating covers on lagoons.
The Knudsen and Sons project in Chico, California, treated wastewater
which contained organic matter from fruit crushing and wash down in a
covered and lined lagoon. The biogas produce is burned in a boiler. And at
Langerwerf Dairy in Durham, California, cow manure is scraped and fed into
a plug flow digester. The biogas produced is used to fire an 85 kW gas
engine. The engine operates at 35 kW capacity level and drives a generator
to produce electricity. Electricity and heat generated is able to offest
all dairy energy demand. The system has been in operation since 1982.
Most anaerobic digestion technologies are commercially available. Where
unprocessed wastes cause odor and water pollution such as in large
dairies, anaerobic digestion reduces the odor and liquid waste disposal
problems and produces a biogas fuel that can be used for process heating
and/or electricity generation.
Technology
assessment
This
section describes the anaerobic digestion (AD) process, outlines
guidelines for assessing the feasibility of AD and biogas usage at a swine
facility and provides summary information on AD system performance and
reliability.
Anaerobic
Digestion Technology Description
AD
promotes the bacterial decomposition of the volatile solids (VS) in animal
wastes to biogas, thereby reducing lagoon loading rates and odor. The
primary component of an AD system is the anaerobic digester, a waste
vessel containing bacteria that digest the organic matter in waste streams
under controlled conditions to produce biogas. As an effluent, AD yields
nearly all of the liquid that is fed to the digester. This remaining fluid
consists of mostly water and is allowed to evaporate from a secondary
lagoon, land-applied for irrigation and fertilizer value or recycled to
flush manure from the swine building to the digester.
The
benefits of AD include:
-
Odor
reduction;
-
Reduction
in the biological oxygen demand of treated effluent by up to 90
percent, reducing the risk for water contamination;
-
Improved
nutrient application control, because up to 70 percent of the nitrogen
in the waste is converted to ammonia, the primary nitrogen constituent
of fertilizer;
-
Reduced
pathogens, viruses, protozoa and other disease-causing organisms in
lagoon water, resulting in improved herd health and possible reduced
water requirements; and
-
Potential
to generate electricity and process heat.
AD
takes place in three steps: hydrolysis, acid formation, and methane
generation. During the first step, hydrolysis, bacterial enzymes break
down proteins, fats and sugars in the waste to simple sugars. During acid
formation, bacteria convert the sugars to acetic acid, carbon dioxide and
hydrogen. Then the bacteria convert the acetic acid to methane and carbon
dioxide, and combine carbon dioxide and hydrogen to form methane and
water.
Digester
technologies that can be used to collect biogas from swine facilities
include:
-
Covered
anaerobic lagoons,
-
Complete
mix digesters and
-
Sequencing
batch reactors.
Although
a sequencing batch reactor has been used for AD at one swine facility in
the
United States
, this technology is considered to be experimental, and thus is not
included in this report. This report focuses on technologies that have
verifiable performance characteristics, namely, covered anaerobic lagoons
and complete mix digesters.
Appendix
B provides contact information that can help producers find AD system
designers/installers, odor control technologies, generators, heating and
cooling equipment, and other information to help manage air and water
quality at hog facilities.
Covered
lagoon digesters are the simplest AD system. These systems typically
consist of an anaerobic combined storage and treatment lagoon, an
anaerobic lagoon cover, an evaporative pond for the digester effluent, and
a gas treatment and/or energy conversion system. Figure 1 shows a typical
schematic for a floating covered anaerobic lagoon.

Source: EPA. (July 1997). AgStar Handbook: A Manual for Developing Biogas
Systems at Commercial Farms in the
United States
. EPA 430-B-97-015.
Washington
,
DC
. pp. 1-3.
Figure
1 . Covered anaerobic lagoon digester
Covered
lagoon digesters typically have a hydraulic retention time (HRT) of 40 to
60 days. The HRT is the amount of time a given volume of waste remains in
the treatment lagoon. A collection pipe leading from the digester carries
the biogas to either a gas treatment system such as a combustion flare, or
to an engine/generator or boiler that uses the biogas to produce
electricity and heat. Following treatment, the digester effluent is often
transferred to an evaporative pond or to a storage lagoon prior to land
application.
Climate
affects the feasibility of using covered lagoon digesters to generate
electricity. Engine/generator systems typically do not produce sufficient
waste heat to maintain temperatures high enough in covered lagoon
digesters in the winter to sustain consistently high biogas production
rates. Using propane or natural gas to provide additional heat for the
lagoon contents is typically not an economically viable option. Without
that additional heat, most covered lagoon digesters produce less biogas in
colder temperatures, and little or no gas below 39 FACE=
"Symbol">° F. As a result, covered lagoon digesters are most
appropriate for use in warm climates if the biogas is to be used for
energy or heating purposes.
Complete
mix digester systems consist of a mix tank, a complete mix digester and a
secondary storage or evaporative pond. The mix tank is either an
aboveground tank or concrete in-ground tank that is fed regularly from
underfloor waste storage below the animal feedlot. Waste is stirred in the
mix tank to prevent solids from settling in the waste prior to being fed
to the digester. The complete mix digester is essentially a
constant-volume aboveground tank or in-ground covered lagoon that is fed
daily from the mix tank. Complete mix digesters with in-ground lagoons
often employ covers similar to those used in covered lagoon digesters. In
the digester, a mix pump circulates waste material slowly around the
heater to maintain a uniform temperature. Hot water from an
engine/generator cogeneration water jacket or boiler is used to heat the
digester. A cylindrical aboveground tank, such as that shown in Figure 2,
optimizes biogas production, but is more capital intensive than in-ground
tanks. The only operating AD system in
Colorado
that recovers methane for energy use is a complete mix digester, located
at Colorado Pork LLC near
Lamar
,
Colorado
.
Source:
EPA. (February 1997). AgStar Technical Series: Complete Mix Digesters –
A Methane Recovery
Option for All Climates. EPA 430-F-97-004.
Washington
,
DC
.
Figure
2 . Complete mix digester schematic
Complete
mix digesters have an HRT of 15 to 20 days, which means that complete mix
digesters can reduce the overall lagoon volume required for waste storage
and treatment. This makes complete mix digesters comparable to covered
lagoon digesters in cost, despite the increased complexity of stirring,
mixing and plumbing components. In addition, biogas production rates, and
therefore heat and electricity production, are greater and more consistent
than for covered lagoons. This can help reduce system payback periods
compared to covered lagoon systems. Like covered lagoon systems, digester
effluent from complete mix digesters is frequently stored in evaporative
ponds or storage lagoons.
System
Requirements
This
section provides guidelines for conducting a preliminary assessment of the
feasibility of using AD at a swine facility. Although AD system
requirements will vary depending on the application and system design,
there are some rule-of-thumb measures that should be noted when assessing
the feasibility of AD at a given location. For AD to potentially be
technically feasible and cost-effective, a swine facility should:
-
Simultaneously
house at least 2,000 animals with a total live animal weight of at
least 110,000 pounds,
-
Have
no more than 20 percent variation in animal population throughout the
year,
-
Collect
waste at one central location such as an underfloor pit,
-
Collect
waste daily or every other day, or can convert to an equivalent
collection system,
-
Have
manure free of large amounts of bedding or other foreign materials,
and
-
Have
some manure storage capability to maintain a steady digester feedstock
supply
If
the above characteristics are present, the facility is a possible
candidate for AD. Many pre-existing waste storage and treatment lagoons
are too large to practically or cost-effectively employ covers over
their entire area. Partial covers may be an option to recover methane
from these older systems, as an alternative to installing a completely
new storage and treatment lagoon system.
If
energy recovery is to be employed, methane production and gas quality
should be considered and compared to energy requirements at the
facility. Daily biogas production at installed farm-based anaerobic
digesters in the
United States
varies from 24,000 to 75,000 cubic feet, or an energy equivalent of 13
to 42 million British thermal units (Btu) (assuming 55 percent methane
content for biogas). Covered lagoon digesters and complete mix digesters
differ in their methane production characteristics, and energy
conversion systems that rely on methane from anaerobic digesters should
be chosen according to the end-use objective for the system. Complete
mix digesters can produce heat and electricity at a constant rate
throughout the year because heat recovery can be used to heat the
digesters in the winter. Covered lagoon digesters can consistently
produce biogas only in months when the temperature exceeds 39 degrees
Fahrenheit.
Facilities
that are located south of the line of climate limitation in Figure 3 are
usually warm enough for cost-effective energy recovery from covered
lagoon digesters. In most cases, facilities north of the climate line in
Figure 3 are too cold for cost-effective energy recovery from covered
lagoon digesters. Complete mix digesters can be used in cold or warm
climates. If odor control is the only objective, either covered lagoon
or complete mix digesters may be used, but odor control will be less
effective in the winter for covered lagoon digesters south of the line
of climate limitation in Figure 3. In general, complete mix digesters
are the most appropriate choice for use in Colorado.
Source: EPA. (July 1997). AgStar Handbook: A Manual for Developing
Biogas Systems at
Commercial Farms in the
United States
. EPA 430-B-97-015. pp. 4-12.
Figure
3 . Line of climate limitation for biogas energy recovery
Table
2 shows which digesters are appropriate for the waste collection
strategies at covered swine facilities. Complete mix digesters can
operate with a waste total solids (TS) percentage between 3 and 10
percent, while covered lagoon digesters can use waste with a TS
percentage less than 2 percent.
Table
2 . Matching a digester to existing waste collection practices
|
Collection
system
|
Percent
TS required
|
Digester
type
|
Suitable
climate
|
|
Scrape
|
3-8
|
Complete
mix
|
Warm
or cold
|
|
Pit
storage
|
3-8
|
Complete
mix
|
Warm
or cold
|
|
Flush
|
<2
|
Covered
lagoon
|
Warm
|
|
Pit
recharge
|
<3
|
Covered
lagoon
|
Warm
|
|
Gravity
drainage
|
|
|
|
|
Pull
plug
|
<2
|
Covered
lagoon
|
Warm
|
|
Managed
pull-plug
|
3-6
|
Complete
mix
|
Warm
or cold
|
Source
– Adapted from: EPA. (July 1997). AgStar Handbook: A Manual for
Developing Biogas Systems at Commercial
Farms in the
United States
. EPA 430-B-97-015. pp. 4-15.
Appendix
C describes each of the various waste collection technologies listed in
Table 2.
Biogas
Utilization Systems
This
section discusses some of the biogas utilization options that are
available for use with AD. Electricity generation with waste heat recovery
(cogeneration) and direct combustion and use in equipment that normally
uses propane or natural gas are the two primary options for biogas
utilization. Electricity generated using biogas can be generated for
on-farm use or for sale to the electric power grid if an economically
attractive power purchase agreement can be negotiated through the local
utility or rural electric cooperative. Direct combustion allows the gas to
be used in existing equipment that normally uses propane or natural gas
such as boilers or forced air furnaces with minor equipment modifications.
Combustion is usually a seasonal use for biogas, as most boiler and
furnace applications are only required during the winter. The EPA FarmWare
manual describes some characteristics of engine/generator and direct
combustion systems that can be used with biogas. The following subsections
draw from the FarmWare manual to provide some basic information about the
use of these systems at covered swine facilities and other farm
applications.
Electricity
Generation
Commercial
electricity generation systems that use biogas typically consist of an
internal combustion (IC) engine, a generator, a control system and an
optional heat recovery system.
IC
engines designed to burn propane or natural gas are easily converted to
burn biogas by adjusting carburation and ignition systems. Such engines
are available in nearly any capacity, but the most successful varieties
are industrial engines that are designed to work with wellhead natural
gas. A biogas-fueled engine will normally convert 18 to 25 percent of the
biogas Btu value to electricity.
Two
types of generators are used on farms: induction generators and
synchronous generators. Induction generators operate in parallel with the
utility and cannot operate as a stand-alone power source. Induction
generators derive their phase, frequency and voltage from the utility.
Synchronous generators operate as an isolated system or in parallel to the
utility, and require more sophisticated intertie systems to match output
to utility phase, frequency and voltage.
Control
systems are required to protect the engine and the utility. Control
packages are available that can shut the engine off due to mechanical
problems, utility power outage or utility voltage and frequency
fluctuations, or in the event that excess power is generated that the
utility will not accept. Generators that operate in parallel with the
utility system, such as induction generators, require an intertie system
with safety relays to shut off the engine and disconnect from the utility
in the event of a problem. Intertie negotiations with a utility for
induction generators are typically much easier than for a synchronous
generator, due to the level of control the utility has over the
characteristics of power entering the grid from an induction generator.
The primary advantage of a synchronous generator is its ability to act as
a stand-alone power source. However, if operated as an isolated system, a
synchronous generator must be oversized to meet the highest electrical
demand, while operating less efficiently at average or partial loads. Due
to the system size and more complicated control requirements, a
synchronous generator operating as an isolated system is typically more
expensive than an induction generator.
Biogas
engines reject approximately 75 to 82 percent of the energy input as waste
heat. This waste heat can be used to heat the digester and/or provide
water or space heat to the facility. Commercial heat exchangers can
recover waste heat from the engine water cooling system and the engine
exhaust, recovering up to 7,000 Btu/hour for each kW of generator load.
Waste heat recovery increases the energy efficiency of the system to 40 to
50 percent.
Ongoing
research and development is focusing on the use of microturbines and fuel
cells for converting biogas to electricity. Microturbines are high-speed,
small-scale (typically less than 100 kW) gas-driven turbine systems that
produce electricity efficiently, have low emissions and require little
maintenance. Reflective Energies in
Viejo
,
California
in partnership with a microturbine
manufacturer is working on
developing a new microturbine that can
use biomethane from animal waste, landfill gas and biomass gasification as its
fuel source. Fuel cells are an emerging technology that operate, in
principle, like a battery, but do not run out of charge. Instead, fuel
cells equipped with a fuel reformer can use any type of hydrocarbon fuel,
and run continuously as long as fuel is available. Fuel cells can convert
fuel to electricity at efficiencies close to 40 percent, compared to 30
percent for the most efficient engine. In addition, fuel cell emissions
include heat, some of which can be recovered for other applications,
water, and carbon dioxide.
The
Department of Energy’s WRBEP funded a project in fiscal year 2000 in
San Luis Obispo
,
California
that will demonstrate electricity generation from methane using a
prototype microturbine at a 350-cow farm. The project will be using a 25
kW microturbine prototype to generate electricity at the California
Polytechnic
State
University’s demonstration farm.
Direct
Combustion
Direct
combustion of biogas on-site in a boiler or forced air furnace can provide
seasonal heat to nurseries, farrowing rooms and other facilities at a
swine facility. A cast iron natural gas boiler can be used for most farm
boiler applications. The air-fuel mixture will require adjustment and
burner jets will need to be enlarged for use with low-Btu gas. Cast iron
boilers are available in many sizes, from 45,000 Btu/hour and up.
Untreated biogas may be used, but all metal surfaces of the boiler housing
should be painted to prevent corrosion. Flame tube boilers with heavy
gauge flame tubes may be used if the exhaust temperature is maintained
above 300 FACE= "Symbol">° F to prevent condensation. Forced
air furnaces can be used in place of direct fire room heaters, but biogas
must be treated to remove hydrogen sulfide because of potential corrosion
problems in metal ductwork.
System
Performance and Benefits of AD
There
are several measures of waste management system performance that are
relevant for producers considering the use of AD. These include:
-
Odor
control,
-
Water
quality protection
-
Energy
production.
AD
is the only waste management strategy available that provides the option
to recover methane for energy production.
The
APCD has determined that the minimum standard for compliance with odor
control regulations for waste vessels and impoundments is an 80 percent
reduction in all odor-causing gases, including hydrogen sulfide, ammonia
and volatile organic compounds from waste vessels or impoundments. Table 3
compares the effectiveness of some of the odor control methods being
implemented at covered swine facilities in
Colorado
. Lagoon covers and AD are among the most effective means of reducing
odors from waste storage and treatment systems. However, several
strategies may be combined to increase the effectiveness of individual
odor control strategies at a facility. As an example, feed additives can
be used in conjunction with biofilters, surface aeration or solids
separation to increase overall odor control from waste storage and
treatment lagoons. In addition, any lagoon odor control technology should
be accompanied by an overall odor management program using best management
practices as described in Appendix D.
Table
3 . Odor control effectiveness of management strategies for
anaerobic lagoons
|
Odor
control technology
|
Percent
(%) odorous gas emissions reduction
|
|
Feed
processing/additives
|
|
|
Grinding
feed
|
5-12
|
|
Wet-feeding
hogs (3:1 water to feed)
|
23-31
|
|
Reducing
sulfur-containing amino acids
|
49-63
|
|
Adding
fiber (soybeans, hulls to diet)
|
Up
to 68
|
|
Biofilters
|
50
|
|
Solids
separation
|
50-60
|
|
Soil
injection of waste upon land application
|
50-80
(land application odors only)
|
|
Surface
aeration
|
Up
to 85
|
|
Aerobic
cap
|
Up
to 90
|
|
Lagoon
additives
|
Up
to 90
|
|
Lagoon
covers
|
80-90
|
|
Anaerobic
digestion
|
80-90
|
|
Composting
|
Up
to 100 for well-managed systems
|
Source:
Iversen, Kirk and Jessica Davis. (February 1999). Innovations in odor
management technology.
Colorado
State
University
. Agricultural and Resource Policy Report. APR-99-02.
Fort Collins
,
CO
.
In
addition to regulating odors from waste lagoons, the new odor control
regulations have requirements for waste that is applied to agricultural
land. The new regulations for waste treatment at covered swine facilities
require that waste applied to agricultural land and not injected be
treated to remove at least 65 percent of the TS and over 90 percent of the
total volatile fatty acids or 60 percent of total VS. If not treated,
waste applied to agricultural land must be injected or knifed into the
soil upon application. Land application is not permitted between November
1 and February 28. Of the waste management strategies in Table 3, four
will help reduce the TS and VS content prior to land application.
-
Wet-feeding,
-
Solids
separation,
-
AD
and
-
Composting.
Wet
feeding can reduce the TS and VS by a value equal to the dilution rate
of the feed (i.e., 3:1 ratio of water to feed). However, introducing
this type of feeding system increases water requirements and may
increase required anaerobic lagoon volumes. Solids separation can reduce
TS by 30 to 45 percent. Solids separation methods include screen
separators, mechanical presses, settling tanks, settling basins, vacuum
filters and many other means. An efficient AD installation will reduce
the TS percentage by up to 76 percent and VS by up to 90 percent. Of the
above technologies, AD with covered anaerobic lagoons is the only one
the APCD considers a proven technology because of their odor control
effectiveness. Therefore, unlike the other options above, covered
anaerobic digesters do not have to meet the additional testing
requirements for technologies that the APCD considers experimental.
Composting
may or may not meet the TS requirement because it often involves the
addition of a bulking agent to increase TS to optimize waste
decomposition. However, composting can be effective at controlling odors
and reducing pathogens. The APCD is presently reviewing the compliance
status of one facility that uses composting. Composting has applications
besides manure treatment for livestock facilities. The Colorado
Governor’s Office of Energy Management and Conservation is currently
supporting the demonstration of composting technology for hog mortality
disposal at a hog farm in
Colorado
.
In
an AD system, most of the organic nitrogen (N) from the digester is
converted to ammonium, an easily manageable fertilizer with slow release
properties when compared to mineralized fertilizers. This is an
advantage over anaerobic lagoons alone. Organic N in the form of protein
and urea is mineralized in soil solution after land application. This
mineralized N can pose a groundwater problem when land-applied because
mineralized N can be converted to nitrates and leach into groundwater in
the spring and fall when plant uptake of N is low.
A
disadvantage of reducing the nutrient content of lagoon effluent via AD
is the loss of the value of nutrients. Reducing the use of lagoon
effluent as fertilizer increases the need for industrial fertilizers,
the manufacture and transportation of which uses significant quantities
of petroleum. However, this loss is balanced by the benefits of
increased control farmers have over the nutrient content of effluent
used for irrigation purposes.
System
Reliability
System
reliability is a key concern for swine producers that are considering AD
with energy recovery as an objective. AD systems first began to be used
extensively after World War II in
Europe
when energy supplies were reduced. Today there are over 600 digesters in
Europe
alone. Farm-based anaerobic digesters are the most common application of
AD technology worldwide. In the
U.S.
, livestock producers have less experience working with anaerobic
digesters, with a total of approximately 160 digesters either planned or
installed in 1998. Of these, 36 employ technology that is suitable for use
at swine facilities.
A
recent survey of anaerobic digesters yielded mixed results for system
reliability (Table 4). At farms across the
U.S.
, the percentage of installed digesters that are not operating is nearly
46 percent. However, one encouraging note is that the reliability of
digesters constructed since 1984 is much greater than for those
constructed between 1972 and 1984.
Table
4 . Status of farm-based digesters at swine facilities in the
United States
|