Net
Energy Balance for Bioethanol Production and Use
Bioethanol
production for transportation fuel is not without environmental
concerns. Current U.S. fuel ethanol production is based almost entirely
on starch from corn grain. To achieve its tremendous production levels,
modern U.S. corn farming makes relatively intense use of energy and
chemicals. Early ethanol plants were also energy intensive, raising
concerns as to whether the transportation fuel being produced was worth
the energy going into making it. American agriculture, however, has made
great efficiency gains in recent years, as has the fuel ethanol industry.
The
most official study of the issue, which also reviews other studies,
concludes that the "net energy balance" of making fuel ethanol
from corn grain is 1.34; that is, for every unit of energy that goes
into growing corn and turning it into ethanol, we get back about
one-third more energy as automotive fuel. That may not sound impressive,
but bear in mind that while the gasoline that ethanol displaces is
largely imported and a high-level pollution source, the mix of energy
inputs for producing bioethanol includes much domestic and relatively
cleaner energy. On the basis of liquid fuels alone, the net balance is
6.34 (USDA Office of Energy Policy and New Uses, The Energy Balance of
Corn Ethanol: An Update).
A
public interest environmental organization study (Institute
for Local Self Reliance), 1995 shows how much net energy balance can
improve. Calculating the current balance at 1.38, it goes on to
calculate a ratio of 2.09, if you base it on corn grown in the most
efficient farming state and ethanol produced in the most efficient
existing facilities. That is, if the industry averages move to the
current industry bests, as you would expect them to tend toward, there
would be more than twice as much energy in the fuel ethanol as went into
making it.
For
cellulosic bioethanol—the focus of the Biomass Program—that study
projects an energy balance of 2.62. That is based on growing and
harvesting energy crops such as fast-growing trees, so bioethanol from
corn stover or other residue that requires no production effort would
have an even more favorable energy balance. A Biomass Program life-cycle
analysis of producing ethanol from stover, now underway, is expected to
show a very impressive net energy ratio of more than 5. It should be
noted, though, that much of the energy gain comes from generating
electricity by burning the co-product lignin, rather than from the
ethanol itself.
One
of the most persistent critics of fuel ethanol [David Pimentel, Cornell
University, (see for example Journal of Agricultural and
Environmental Ethics, vol. 4, no. 1, pp. 1-13. 1991.)] asserts that
it takes about 70% more energy to grow corn and make ethanol from it
than goes into the ethanol. Among other things, however, his analysis is
based on old data and does not give any credit for the energy value of
the animal feed co-product of making ethanol (both dry-mill- and
wet-mill-ethanol plants produce high-protein animal feeds as a major
co-product, a key economic element of the production processes). The use
of old data is significant because the modern ethanol industry is only
about 20 years old and plants today are far more efficient than the
first ones built. Productivity of corn production has also increased
dramatically.
Ethanol
critics also question the wisdom of growing fuel instead of food, but
corn (field corn, not to be confused with sweet corn) is used mostly for
livestock feed and for products such as beverage sweeteners, rather than
direct human consumption. As the largest U.S. agricultural crop, it is
generally in surplus, requiring price supports, so to whatever extent
ethanol supports corn prices, taxpayer costs are reduced. Cellulosic
bioethanol production would have even less impact on food supplies. It
would use either residues such as stover that are produced as a
byproduct of producing other crops or dedicated
energy crops grown on land not economically suitable for food crops.
With
lower fertilizer requirements for soybeans than corn and simpler
processing, biodiesel production and use has a net energy balance of
3.2.
Biofuel
Feedstocks
www.BiofuelFeedstocks.com
What
are Biofuel Feedstocks?
Biofuel
feedstocks are the organic materials used in the production of biofuels
such as: Biomethane, B100
Biodiesel and E100 Ethanol.
Biomethane
(also known as "Renewable Natural
Gas") generates the highest net energy balance of
all biofuels which means that it's much more efficient and economic to
produce Biomethane with ANY of the potential
biofuel feedstocks that may have been otherwise used to produce B100
Biodiesel or E100 Ethanol.
The
most efficient method of generating Biomethane
is through a process called Biomass
Gasification.
Examples
of biofuel feedstocks include:
For
Biomethane: any organic
materials - i.e. grass, leaves, corn, sugar beets, sugar cane, crude
canola oil, crude coconut oil, crude
jatropha oil, crude palm oil, crude
rapeseed oil, which are those typical biofuel feedstocks used to
produce B100 Biodiesel or E100
Ethanol.
What are
"biofuels"?
Biofuels are "biorenewable
energy" resources that replace non-renewable fossil fuels (crude
oil, gasoline, propane, natural gas, etc.). Since the carbon found
in biofuels are found in plants and therefore "grown" through
photosynthesis of plants, there are no net carbon emissions when biofuels
are burned or combusted. This means that when biofuels replace
non-renewable fossil fuels, greenhouse gas emissions, and carbon dioxide
emissions are reduced. Biofuels include Biomethane,
B100 Biodiesel, and E100
Ethanol. For example, Biomethane
is the "natural" gas that is produced from the anaerobic
decomposition of organic material in a landfill. While Biomethane normally
contain about half the btu content of typical natural gas sold by gas
companies, Biomethane is a substitute form and completely replaces natural
gas. Likewise, B100
Biodiesel is a substitute and completely replaces petroleum
diesel on a gallon for gallon basis as does E100
Ethanol, which replaces gasoline on a gallon for gallon basis.
Our company
develops, builds, owns, operates, acquires and invests in facilities that produce Biomethane,
B100 Biodiesel, and E100
Ethanol. We buy, sell, and
broker other biofuels and commodities/feedstocks used in making B100
Biodiesel and E100 Ethanol. These feedstocks include Crude Palm Oil,
Refined Palm Oil, Coconuts, Palm Oil, and we are also looking into the use
of Jatropha and
other biorenewable energy oils, where we refine it into
B100 Biodiesel
fuel for use in our
cogeneration and trigeneration power plants. Additionally, we
buy/sell/broker energy oils in the international markets.
Biofuel
Industries is a subsidiary of Renewable Energy Technologies now
re-locating from Houston to Austin, Texas. We provide the following power and energy project
development services:
-
Project
Engineering Feasibility & Economic Analysis Studies
-
Engineering,
Procurement and Construction
-
Environmental
Engineering & Permitting
-
Project
Funding & Financing Options; including Equity Investment, Debt
Financing, Lease and Municipal Lease
-
Shared/Guaranteed
Savings Program with No Capital Investment from Qualified Clients
-
Project
Commissioning
-
3rd
Party Ownership and Project Development
-
Long-term
Service Agreements
-
Operations
& Maintenance
-
Green
Tag (Renewable Energy Credit, Carbon Dioxide Credits, Emission
Reduction Credits) Brokerage Services; Application and Permitting
We
provide Net Energy Metering project development services as well as
"turnkey" products and services in the areas of "Renewable
Energy Technologies" and in developing clean power/energy
projects that will generate a "Renewable
Energy Credit," Carbon
Dioxide Credits and Emission
Reduction Credits. Through our strategic partners, we offer
"turnkey" power/energy project development products and services
that may include; Absorption Chillers,
Adsorption Chillers, Automated
Demand Response, Biodiesel
Refineries, Biofuel Refineries, Biomass
Gasification, BioMethane, Canola
Biodiesel, Coconut Biodiesel, Cogeneration,
Concentrating Solar Power, Demand
Response Programs, Demand Side
Management, Energy
Conservation Measures, Energy
Master Planning, Engine Driven
Chillers, Solar CHP, Solar
Cogeneration, Rapeseed Biodiesel,
Solar Electric Heat Pumps, Solar
Electric Power Systems, Solar
Heating and Cooling, Solar
Trigeneration, Soy Biodiesel, and Trigeneration.
Unlike
most companies, we are equipment supplier/vendor neutral. This means we
help our clients select the best equipment for their specific application.
This approach provides our customers with superior performance, decreased
operating expenses and increased return on investment.
For more information: call us at: 832-758-0027
We plan to be a leading supplier of Biodiesel and turnkey Biodiesel Refineries.
For qualified clients, we provide "turnkey" biodiesel refinery
services, including;
EPC (Engineering, Procurement, Construction), Investment/Funding,
Permitting, Carbon Dioxide Credits
and Emission Reduction Credits under the
Kyoto Protocol's Clean Development Mechanism. For more information,
call (832) 758 - 0027
We
buy and sell Biodiesel and have plans to start producing and blending our
own, "home-grown, clean, renewable, and American made" B100
Biodiesel, to help end our reliance on unstable, non-renewable, and
"dirty" middle-east oil that pollutes our environment and causes
inflated energy prices.
B100
Biodiesel (see www.B100Biodiesel.com)
has numerous advantages to petroleum diesel - it's renewable, non-toxic,
biodegradable, and produced by American and Canadian farmers. B100
Biodiesel is 100 % biodiesel fuel, and reduces greenhouse gas emissions by
78.3%, particulate matter by 55.4%, hydrocarbons by 56.3%, mutagenicity by
80-90% and sulfur by 100%.
Our
company invests in and builds new Biodiesel Refineries throughout the
U.S., Canada, Central America and the Caribbean for our company and our
investors. For individual farmers, we can design, engineer and build
small-scale biodiesel refineries; i.e. 5,000 acres of canola will produce
about 500,000 gallons of Biodiesel. We are a broker and importer of
Crude Palm Oil and other energy oils, where we refine it into Biodiesel
fuel for use in our cogeneration and trigeneration power plants.
Additionally,
we buy/sell/broker biofuels, including biodiesel which we can also blend
through our partner companies' facilities anywhere from a B2 to B99
Biodiesel blend. We buy/sell/broker ethanol and energy oils in the
international markets.
Grow Your
Own "Green" BioDiesel
Increase Profits for Farmers,
Improve the Local and Global Economy and Ecology, Decrease Pollution and End the Monopoly of OPEC/Foreign Supplies of
"Dirty" Fuels!
At an average production rate of 130
gallons per acre, Canola or Rapeseed Oil ("BioDiesel") is one of
the preferred energy crops in the U.S. and Europe.
What is Rapeseed Biodiesel?
Rapeseed, some varieties of which are used to make mustard and others to make canola oil, is the preferred biodiesel feedstock in Europe.
Depending on the variety, rapeseed oil contains about 40 to 50 percent of
its weight in rapeseed is oil, as compared with only 20 percent for soybeans. It can be planted and harvested with the
same equipment used for small grains. In addition, rapeseed oil offers certain advantages in the production of biodiesel.
Biodiesel produced from canola and rapeseed oil is superior to soy biodiesel.
Especially due to the widely varying price fluctuations of soybeans. And
because the feedstock (the oil produced from the fuel crop, such as
soybeans, rapeseed or canola) to make biodiesel makes up about 80% of the
cost for
100 % biodiesel, basic economics dictate that the feedstock be obtained
from the least-cost source, which is going to be either canola or
rapeseed.
What is Canola Biodiesel?
Canola biodiesel is an environmentally- friendly, renewable energy source that could also produce cost savings for taxpayers and private
businesses and is produced from farmers that grow canola.
Initial research conducted by the University of Saskatchewan and the AAFC Saskatoon Research Centre has found that each ton of renewable biodiesel fuel saves five times its weight in diesel fuel. As well, engines using biodiesel demonstrate wear rates as much as 50% lower than those using regular commercial fuels – effectively doubling engine life.
Canola is a member of the Brassica Family, which includes broccoli, cabbage,
cauliflower, mustard, radish, and turnip. It is a variant of the crop rapeseed. Grown for its seed, the seed
is crushed for the oil contained within. After the oil is extracted, the by-product is a protein-richmeal used by the intensive livestock industry.
Canola is a very small seed, which means sowing depth must be controlled.
The current sowing practice is to cover the seed lightly with soil, which
provides more protection from drying out after germination.
Canola is generally sown in autumn and develops over winter, with flowers
emerging in the spring and is harvested early summer. With a growing
period of around 180-200 days climatic effects such as sudden heat waves can reduce yields and hot dry conditions can
limit its oil content. Summer weather ensures low moisture (less than 6%) at harvest. Carry-in
stocks of canola are minimal because of a lack of on-farm storage. Canola is a good rotational crop, acting as a break crop for cereal root diseases. However
for disease-related reasons, a rotation period of 3-5 years is required for canola crops.
of iodine in grams absorbed per 100 ml of oil is then the IV. The higher the IV, the
more unsaturated (the greater the number of double bonds available) is the oil and the higher
the potential to ‘gum up’ when used as a fuel in an engine. Though some oils have a low IV and are suitable without any further processing other
than extraction and filtering, the majority of vegetable and animal oils have an IV which does
not permit their use as a neat fuel.
Generally speaking, an IV of less than about 25 is required if the neat oil is to be used
in unmodified diesel engines and this severely limited the types of oil that can be used.
The IV can be easily reduced by hydrogenation of the oil (reacting the oil with hydrogen),
the hydrogen breaking the double bond and converting the fat or oil into a more saturated oil
and reducing the tendency of the oil to polymerise. However this process also tends to increase
the melting point of the oil and converts the oil into margarine. Only coconut oil has an IV low enough to be used without
any special precautions in a unmodified diesel engine. However with a melting point of 25°C,
the use of coconut oil in cooler areas would obviously lead to problems.
Linseed oil could be mixed with petroleum diesel at a
ratio of up to 1:8 to give an equivalent IV in the mid-twenties. Likewise coconut oil can be thinned with diesel or kerosene to render it less viscous in cooler climates. Obviously
the solubility of the oil in petroleum also needs to be taken into account. Another method is
to emulsify the oil or fat with ethanol. Most vegetable oils are a mixture of different esters such as oleic acid (main constituent
of olive oil), ricinoleic acid (main constituent of castor oil), linoleic acid
(main constituents of linseed oil), palmitic acid (main constituent of palm kernel oil) and so on.
In an analogous way to that in which crude oil is refined to make a useable automotive
fuel, canola oil needs to be transesterified to make an automotive fuel that is useable in
unmodified diesel engines.
When the oil is processed in a transesterfication process, the various fatty
acids react with the alcohol to form a mixture of lighter esters and glycerol. The name of
the specific fuel is called after the plant (or animal) source plus the alcohol. Made from
rapeseed oil and methanol, the biodiesel is called Rape Methyl Ester (RME), from canola oil
and ethanol, Canola Ethyl Ester (CEE), and from used McDonald’s cooking oil and ethanol
or methanol, ("McDiesel").
What is "Global
Warming Potential?
Global Warming Potential (GWP) is the index used to translate the level of emissions of various gases into a common measure in order to compare the relative radiative forcing of
different gases without directly calculating the changes in atmospheric concentrations.
GWPs are calculated as the ratio of the radiative forcing
that would result from the emissions of one kilogram of a greenhouse gas to that from emission of one kilogram of carbon dioxide over a period of
time (usually 100 years). Gases involved in complex atmospheric chemical processes have not been assigned GWPs due to complications that arise.
Greenhouse gases are expressed in terms of Carbon Dioxide Equivalent. The International Panel on Climate Change (IPCC) has presented these GWPs
and regularly updates them in new assessments. The instantaneous radiative forcing that results from the addition of 1 kilogram of a gas to the
atmosphere, relative to that of 1 kilogram of carbon dioxide.
Over a time horizon of 100 years, methane has a GWP of 24.5, nitrous oxide has a GWP
of 320, and CFC-11 has a GWP of 4,000
What Are Greenhouse Gases?
Some greenhouse gases occur naturally in the atmosphere, while others result from human activities. Naturally
occurring greenhouse gases include water vapor,
carbon dioxide, methane, nitrous oxide, and ozone. Certain human activities, however, add to the levels of most of these naturally occurring gases:
Carbon dioxide is released to the atmosphere when solid waste, fossil fuels (oil, natural gas, and coal), and wood and wood products are burned.
Methane is emitted during the production and transport of coal, natural gas, and oil. Methane emissions also result from the decomposition of organic wastes in municipal solid waste landfills, and the raising of livestock. More information on methane.
Nitrous oxide is emitted during agricultural and industrial activities, as well as during combustion of solid waste and fossil fuels.
Very powerful greenhouse gases that are not naturally occurring include hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride (SF6), which are generated in a variety of industrial processes.
Global Warming Potentials and Atmospheric
Lifetimes (Years)
|
Gas
|
Atmospheric Lifetime
|
GWPa
|
|
Carbon dioxide (CO2)
|
|
|
|
Methane (CH4)b
|
|
|
|
Nitrous oxide (N2O)
|
|
|
|
HFC-23
|
|
|
|
HFC-32
|
|
|
|
HFC-125
|
|
|
|
HFC-134a
|
|
|
|
HFC-143a
|
|
|
|
HFC-152a
|
|
|
|
HFC-227ea
|
|
|
|
HFC-236fa
|
|
|
|
HFC-4310mee
|
|
|
|
CF4
|
|
|
|
C2F6
|
|
|
|
C4F10
|
|
|
|
C6F14
|
|
|
|
SF6
|
|
|
a 100 year time horizon
b The methane GWP includes the direct effects and those
indirect effects due to the production of tropospheric ozone and
stratospheric water vapor. The indirect effect due to the production of CO2
is not included.
For more information call: 832 - 758 - 0027
We provide turnkey services that removes Nitrogen
Oxides, Nitrous Oxides and Sulfur Oxides. Unlike most
companies, we are equipment supplier/vendor neutral. This means we help
our clients select the best equipment for their specific application. This
approach provides our customers with superior performance, decreased
operating expenses and increased return on investment. Selective
Catalytic Reduction systems are frequently used in removing NOx.
What are Nitrogen Oxides?
Nitrogen oxides, or NOx, is the generic term for a group of highly reactive gases, all
of which contain nitrogen and oxygen in varying amounts. Many of the
nitrogen oxides are colorless and odorless. However, one common pollutant,
nitrogen dioxide (NO2) along with particles in the air can
often be seen as a reddish-brown layer over many urban areas.
Nitrogen oxides form when fuel is burned at high temperatures, as in a
combustion process. The primary sources of NOx are motor vehicles,
electric utilities, and other industrial, commercial, and residential
sources that burn fuels.

Reasons for Concern
|
Nitrogen
Oxides
-
are
one of the main ingredients involved in the formation of
ground-level ozone, which can trigger serious respiratory
problems.
-
reacts to form nitrate particles, acid aerosols, as well as
NO2, which also cause respiratory problems.
-
contributes to formation of acid rain.
-
contributes to nutrient overload that deteriorates water
quality.
-
contributes to atmospheric particles, that cause visibility
impairment most noticeable in national parks.
-
reacts to form toxic chemicals.
-
contributes to global warming.
NOx and the pollutants formed from NOx
can be transported over long distances, following the
pattern of prevailing winds in the U.S. This means that problems
associated with NOx are not confined to areas where NOx are
emitted. Therefore, controlling NOx is often most effective if
done from a regional perspective, rather than focusing on sources
in one local area.
NOx emissions are increasing.
Since 1970, EPA has tracked emissions of the six principal air
pollutants - carbon monoxide, lead, nitrogen oxides, particulate
matter, sulfur dioxide, and volatile organic compounds. Emissions
of all of these pollutants have decreased significantly except for
NOx which has increased approximately 10 percent over this period
|
How can Nitrogen Oxides be Removed from the
Environment?
Selective Catalytic Reduction (SCR) is a proven and effective method to reduce nitrogen
oxides which is an air pollutant associated with the power generation
process. Nitrogen oxides are a contributor to ground level ozone.
How does Selective Catalytic Reduction work?
SCR Systems work similar to a catalytic converter used to reduce automobile emissions. Prior to exhaust gases going up the smokestack, they will pass through the SCR
System where anhydrous ammonia reacts with nitrogen oxide and converts it to nitrogen and water.
* Some of the above information from the Department
of Energy website with permission.
|